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Highly resolved emission of [Os(bpy-h₈)n(bpy-d₈)3-n]²⁺ (n = 0-3: Evidence for electronic delocalization

Huber, P. ; Yersin, Hartmut


Highly resolved emission spectra of the title compounds doped into single-crystal [Zn(bpy-h₈)₃](ClO₄)₂ have been recorded at 1.3 K. The partially deuterated dopants (n = 1, 2) occupy different sites in the host matrix. It is possible to excite site selectively the dominant site (designated B) for both compounds. Properties of the lowest excited electronic states of ³MLCT character of these sites ...


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