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Highly resolved optical spectra of Pd(thpy)₂ in a Shpol'skii matrix

Yersin, Hartmut ; Schützenmeier, S. ; Wiedenhofer, H. ; v. Zelewsky, A.


Pd(2-thpy)₂ is a representative of the interesting new class of ortho-metalated compounds. For the first time, we present highly resolved emission and excitation spectra. This could be achieved by using the Shpol’skii matrix isolation technique. From the intensity distribution of the highly resolved vibrational satellite structures and the corresponding vibrational energies it is concluded that ...


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