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Spectroscopic properties of [Ru(bpy)₂(bpz)]²⁺

Schmidt, J. ; Wudy, J. ; Huber, P. ; Domel, H. ; Braun, D. ; Yersin, Hartmut


We report on the temperature and magnetic field dependence of the low-temperature emission and excitation spectra of [Ru(bpy)₂(bpz)]²⁺ doped into [Zn(bpy)₃](ClO₄)₂. We could identify, for the first time, the origins corresponding to the three lowest electronic states. They are assigned to be triplet sublevels of a Ru4d - (bpy)π* metal to ligand charge transfer (MLCT) excitation. The energies of ...


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