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Ring-substituted 1,2-dialkylated 1,2-bis(hydroxyphenyl)ethanes. 1. Synthesis and estrogen receptor binding affinity of 2,2'- and 3,3'-disubstituted hexestrols

Hartmann, Rolf W. ; Schwarz, Walter ; Schönenberger, Helmut



Abstract

The syntheses of sym. 3,3'- and 2,2'-disubstituted meso hexestrol derivs. (I) are described (3,3'-R = : OH (II) [79199-51-2], F (III) [74536-61-1], Cl (IV) [79140-57-1], Br [74536-64-4], I [55508-15-1], CH2NMe2 [85720-37-2], Me [10465-10-8], CH2OMe [85720-38-3], CH2OEt [85720-40-7], CH2OH [85720-41-8], NO2 [66877-40-5], NH2 [66877-41-6], NMe2 [85720-42-9], Ac [85720-43-0], and Et [85720-45-2]; ...

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