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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Journal or Publication Title: | Chemische Berichte | ||||
| Publisher: | Wiley-VCH Verl. | ||||
| Volume: | 124 | ||||
| Number of Issue or Book Chapter: | 11 | ||||
| Page Range: | pp. 2381-2389 | ||||
| Date: | 1991 | ||||
| Additional Information (public): | CAN 115:269104 78-7 Inorganic Chemicals and Reactions 135147-66-9P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and crystal structure and hydrogenation of); 93913-21-4P; 93913-22-5P; 135147-70-5P; 135147-71-6P; 135147-72-7P; 135147-79-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and ether cleavage reaction of); 135147-68-1P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. and hydrogenation and reaction of, with triphenylphosphine); 135147-65-8P; 135147-77-2P; 135147-85-2P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and hydrogenation of); 128539-38-8P; 135189-77-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction of, with azide); 135147-76-1P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction of, with hydrobromic acid); 135147-80-7P; 135147-82-9P; 135147-84-1P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction of, with tetrachloroplatinate); 135147-81-8P; 135147-83-0P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction of, with tetraiodoplatinate); 135147-69-2P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction of, with triphenylphosphine); 22719-00-2P; 135147-67-0P; 135147-78-3P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and redn. of); 5700-60-7P; 74255-76-8P; 93856-33-8P; 135147-73-8P; 135147-74-9P; 135147-75-0P; 135147-86-3P; 135147-87-4P; 135147-88-5P; 135147-89-6P; 135147-90-9P; 135147-91-0P; 135189-76-3P; 135268-05-2P; 135268-06-3P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 10025-99-7; 14708-56-6 (Dipotassium tetraiodoplatinate(2-) Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with (hydroxyphenyl)phenylethylenediamines); 27356-33-8 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with ammonia followed by reaction with titanium tetrachloride); 603-35-0 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with diazidodiphenylethanes); 22711-21-3; 34082-43-4 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with hydroxylamine); 1694-19-5; 14064-41-6; 52805-92-2 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with iodine azide); 25725-55-7 Role: RCT (Reactant), RACT (Reactant or reagent) (redn. of, aziridine compd. by) | ||||
| Institutions: | Chemistry and Pharmacy > Institute of Pharmacy > Alumni or Retired Professors > Prof. Schönenberger | ||||
| Projects: | SFB 234 | ||||
| Identification Number: |
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| Keywords: | Crystal structure Molecular structure (of diazido(methoxyphenyl)phenylethane) crystal structure azidohydroxyphenylethylenediamine platinum hydroxyphenylethylinediamine complex ethylenediamine hydroxyphenyl platinum complex azidohydroxyphenylethylenediamine prepn structure | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 17688 |
Abstract
erythro- And threo-PtLCl2 (L = 1-(R-substituted) (phenyl)-2-phenyl-1,2-ethanediamine (R = 2-, 3-, 4-OH)) were synthesized. The diastereoisomeric 1-(3-hydroxyphenyl)-2-phenyl-1,2-ethanediamines and threo-1-(2-hydroxyphenyl)-2-phenyl-1,2-ethanediamine were obtained by redn. of the 1,2-diazidoethanes. The configuration of threo-1,2-diazido-1-(2-methoxyphenyl)-2-phenylethane (I) was elucidated by ...
Abstract
erythro- And threo-PtLCl2 (L = 1-(R-substituted) (phenyl)-2-phenyl-1,2-ethanediamine (R = 2-, 3-, 4-OH)) were synthesized. The diastereoisomeric 1-(3-hydroxyphenyl)-2-phenyl-1,2-ethanediamines and threo-1-(2-hydroxyphenyl)-2-phenyl-1,2-ethanediamine were obtained by redn. of the 1,2-diazidoethanes. The configuration of threo-1,2-diazido-1-(2-methoxyphenyl)-2-phenylethane (I) was elucidated by x-ray anal. The redn. of the erythro-1,2-diaryl-1,2-diazidoethanes, substituted with a MeO group in o- or p-position, results in elimination reactions with formation of side products. The desired 1,2-diaryl-1,2-ethanediamines were finally synthesized via either an aziridine deriv. or by redn. of the resp. dioximes. The diamine ligands were converted to PtLC2. I is monoclinic, space group P21/n, a 1017.5(6), b 833.7(6), c 1448.6(2) pm, beta 98.53 Deg, Z = 4, Rw = 0.093.
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