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Stereoisomeric dichloro[1-(hydroxyphenyl)-2-phenyl-1,2-ethanediamine]platinum(II) complexes. I. Synthesis

Müller, Richard ; Gust, Ronald ; Klement, Ulrich ; Schönenberger, Helmut


erythro- And threo-PtLCl2 (L = 1-(R-substituted) (phenyl)-2-phenyl-1,2-ethanediamine (R = 2-, 3-, 4-OH)) were synthesized. The diastereoisomeric 1-(3-hydroxyphenyl)-2-phenyl-1,2-ethanediamines and threo-1-(2-hydroxyphenyl)-2-phenyl-1,2-ethanediamine were obtained by redn. of the 1,2-diazidoethanes. The configuration of threo-1,2-diazido-1-(2-methoxyphenyl)-2-phenylethane (I) was elucidated by ...


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