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Tumor inhibiting [1,2-bis(difluorophenyl)ethylenediamine]dichloroplatinum(II) complexes. I. Synthesis

Müller, Richard ; Schickaneder, Edith ; Jennerwein, Margaretha ; Reile, Herta ; Spruss, Thilo ; Engel, Juergen ; Schönenberger, Helmut


meso- And DL-[NH2CH(C6H3X2)]2 (L; X2 = 2,3-, 2,4-, 2,5-, 2,6-, 3,4-, 3,5-F2) were prepd. from meso-[NH2CH(C6H4OH)]2 and the resp. benzaldehydes by a diazo-Cope rearrangement. L reacted with K2PtX4 (X = Cl, I) to give PtLCl2 and PtLI2 (X2 = 2,4- and 2,6-F2) and PtLI reacted with Ag2SO4 to give PtL(SO4).

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