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(1,2-Diaryl-1,2-ethylenediamine)platinum(II) complexes with sulfato and 3-sulfopropionato leaving groups: investigations with different types of coordination in the solid state, in solution and reactions with nucleophiles

Müller, Richard ; Bednarski, Patrick J. ; Schönenberger, Helmut


The syntheses, solid state and soln. chem., and the in vitro cytotoxic activities of H2O sol. (1,2-diaryl-1,2-ethylenediamine)platinum(II) complexes, having either the sulfato or the novel sulfopropionato anionic leaving group, are described. The compds. were prepd. by allowing the (1,2-diaryl-1,2-ethylenediamine)diiodoplatinum(II) complexes and either Ag2SO4 or Ag sulfopropionate to react in ...


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