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Highly resolved emission of tris(2,2'-bipyridine-d₈) osmium(2+)

Yersin, Hartmut ; Huber, P. ; Braun, D.


The title compound doped into host matrix of single-crystal [Ru(bpy-h₈)₃](ClO₄)₂ exhibits highly resolved emission spectra at low temperatures. The electronic origins of the three lowest excited states lying at 14201 ± 1 cm⁻¹ (line I), 14261 ± 1 cm⁻¹ (line II), and 14415 ± 3 cm⁻¹ (line III) are determined. Further, a large number of vibronic components are identified. The radiative decay paths ...


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