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Fine structure in the emission spectrum of [Ru(bpy)₃](PF₆)₂ single crystal

Hensler, G., Gallhuber, E. and Yersin, Hartmut (1986) Fine structure in the emission spectrum of [Ru(bpy)₃](PF₆)₂ single crystal. Inorganica Chimica Acta 113, pp. 91-94.

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For the first time, highly resolved polarized emission spectra of single-crystal [Ru(bpy)₃] (PF₆)₂ are presented. At low temperatures (T < 20 K) we observed fine structure on the blue side of the emission spectrum with a typical halfwidth of <=5 cm⁻¹. The spectral properties of the sharp emission lines and their temperature dependences allow us to assign two zero-phonon lines corresponding to 1E’ —› A’₁ at 17809 cm⁻¹ and to 2E’ —› A’₁ at 17816 cm⁻¹ in the D'₃ symmetry group.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17751
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