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Low-temperature emission spectra of crystalline [Ru(bpy)₃](ClO₄)₂

Gallhuber, E. ; Hensler, G. ; Yersin, Hartmut


The three lowest excited states of crystalline [Ru(bpy)₃](CIO₄)₂ and their energies of 17605, 17614, and 17663 cm⁻¹ are identlfied by three zero-phonon lines in the emission spectra. A broad-band system and the zero-phonon lines show the same temperature dependence and belong to the same states. Each zero-phonon line is accompanied by a low-frequency progression of 36 cm⁻¹. Satellites due lo ...


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