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Abstract
Polarized emission spectra of single-crystal [Ru(bpy)₃](PF₆)₂ are reported for the first time. The spectra are recorded in the temperature range from T = 243 to 343 K. A new E parallel c-polarized emission band is found, situated 650 cm⁻¹ ± 20 % above the main emission peak maximum. The corresponding emitting state is assigned to A₂' (in D₃'). The E perpendicular c-polarized emission results from ...
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