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Pressure induced phase transition in the highly anisotropic compounds: Y₂[Pt(CN)₄]₃•21H₂O

Daniels, W., Yersin, Hartmut, Stock, M. and Gliemann, G. (1981) Pressure induced phase transition in the highly anisotropic compounds: Y₂[Pt(CN)₄]₃•21H₂O. Solid State Communications 40, pp. 937-938.

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For the linear chain system Y₂[Pt(CN)₄]₃•21H₂O a pressure induced phase transition is observed by emission spectroscopy. At p(trans) = (5 ± 0.5) kbar and T = 295 K the compound undergoes a first order phase transition, in the course of which the intra-chain Pt-Pt distance R shrinks by ΔR ca. -0.03Å. An approximate value had already been found at standard pressure for a temperature induced phase transition (T(trans) = 218 K).

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17766
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