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Luminescence quenching and exciton dynamics in quasi-one-dimensional mixed crystals: Ba[Pt1-xNix(CN)₄]•4H₂O

Yersin, Hartmut ; Holzapfel, W. ; Gliemann, G.


Doping of [Ni(CN)₄]²⁻ complexes into Ba[Pt(CN)₄]•4H₂O single crystals quenches selectively the host emission. We studied the concentration dependence at different temperatures up to one mole percent [Ni(CN)₄]²⁻. It is shown that (at 80 K and x = 10⁻²) the E perpendicular c polarized emission (E = electric field vector, c = stack axis) is quenched by a factor of about 10³ without any intensity ...


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