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Fast Thermal Breaking and Formation of a B–N Bond in 2-(Aminomethyl)benzeneboronates

Burgemeister, Thomas, Grobe-Einsler, Ronald, Grotstollen, Reiner, Mannschreck, Albrecht and Wulff, Günter (1981) Fast Thermal Breaking and Formation of a B–N Bond in 2-(Aminomethyl)benzeneboronates. Chemische Berichte 114 (10), pp. 3403-3411.

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The Title compounds 1 to 6 (Table 1) are shown by 1H, 11B, and 15N NMR shifts to fom an intramolecular B - N bond which, according to 1N and 13C NMR, is frequently broken (δ G math image = 40 to 54 kJ/mol, Table 2) and re-formed.

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Item type:Article
Additional Information (public):späterer Zeitschr.titel: European journal of inorganic chemistry
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Prof.Dr. Mannschreck
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:17969
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