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Protonenresonanz-Untersuchungen zur inneren Rotation 3: Comparison of kinetic results obtained by NMR line shape and equilibration methods

Mannschreck, Albrecht, Mattheus, A. and Rissmann, G. (1967) Protonenresonanz-Untersuchungen zur inneren Rotation 3: Comparison of kinetic results obtained by NMR line shape and equilibration methods. Journal of molecular spectroscopy 23 (1), pp. 15-31.

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Abstract

Rates of internal rotation around carbonyl-to-nitrogen bonds are determined for the rotamers IA and IB of N-benzyl-N,2,4,6-tetramethylbenzamide by equilibration of IA and for N,N,2,4,6-pentamethylbenzamide (II) by 1H-NMR line shapes. The activation parameters (Table V) obtained by the two methods agree well within error limits. This represents the first experimental confirmation of the soundness ...

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Item type:Article
Date:1967
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Prof.Dr. Mannschreck
Identification Number:
ValueType
10.1016/0022-2852(67)90044-6DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:17996
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