Go to content
UR Home

Protonenresonanz-Untersuchungen zur inneren Rotation 3: Comparison of kinetic results obtained by NMR line shape and equilibration methods

Mannschreck, Albrecht ; Mattheus, A. ; Rissmann, G.


Rates of internal rotation around carbonyl-to-nitrogen bonds are determined for the rotamers IA and IB of N-benzyl-N,2,4,6-tetramethylbenzamide by equilibration of IA and for N,N,2,4,6-pentamethylbenzamide (II) by 1H-NMR line shapes. The activation parameters (Table V) obtained by the two methods agree well within error limits. This represents the first experimental confirmation of the soundness ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons