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Enantiomeric local anesthetics of the N-aminoacyl-2,6-dimethylaniline type

Schönenberger, Helmut ; Petter, Alfred ; Zwez, W.


Enantiomeric N-aminoacyl-2,6-dimethylanilines were synthesized by condensation of optically active N,N-dimethylalanines or phenylalanines with EtO2- CCl, yielding mixed anhydrides. Reaction of these with 2,6-Me2C6H3NH2 gave optically active N-aminoacyl-2,6-dimethylanilines. Compds. synthesized were [m.p. HCl salt and [alpha ]20D (c, 0.5, H2O) given]: N-(D-N, N-dimethylalanyl)-2,6-dimethylaniline, ...


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