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Cystostatic agents. III. Mechanism of reduction of Schiff bases by activated aluminum

Schönenberger, Helmut ; Thies, Heinrich ; Rappl, A.



Abstract

cf. Schoenenberger, et al., CA 62, 6992f, 7664a, 13163g. The mechanism of redn. was investigated of benzylidenealkyl- and benzylidenearylamine-type Schiff bases with activated Al, to form mono- and dimeric secondary amines. Redn. of PhCH:NBu (I) in abs. EtOH with Al-Hg gave yields of benzylbutylamine (II) and N,N'-dibutyl-alpha ,alpha '-diphenylethylenediamine (III) (in meso- and racemic forms) ...

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