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Reactions of alpha -aminonitriles. VI. Reactions of aliphatic-substituted alpha -aminoacetonitriles with metallic sodium in toluene

Thies, Heinrich, Schönenberger, Helmut and Qasba, P. K. (1969) Reactions of alpha -aminonitriles. VI. Reactions of aliphatic-substituted alpha -aminoacetonitriles with metallic sodium in toluene. Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft 302 (8), pp. 610-617.

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To 17.2 g. Na in 250 ml. PhMe 0.75 mole I in 250 ml. PhMe was added dropwise with slow shaking, and the mixt. shaken 4 hrs. at 120 Deg to give mixts. of II and III (R, R1, b.p. II, % yield II, b.p. III, and % yield III given): H, Me, b720 130-2 Deg, 43.3, b15 148 Deg, 21.8; H, Pr, b725 171-8 Deg, 42.1, b15 173-5 Deg, 21.2; Me, Me, b720 145-8 Deg, 51.9, b0.4 110-13 Deg, 7.8; Me, Et, b715 173-5 ...


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Item type:Article
Additional Information (public):CAN 71:124154 27 Heterocyclic Compounds (One Hetero Atom) 766-09-6P; 766-79-0P; 782-07-0P; 785-94-4P; 4945-48-6P; 24114-07-6P; 24114-09-8P; 25991-45-1P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 3010-03-5D (1-Piperidineacetonitrile) Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with sodium in toluene); 7440-23-5 Role: RCT (Reactant), RACT (Reactant or reagent) (with piperidineacetonitrile alkyl derivs. in toluene)
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Alumni or Retired Professors > Prof. Schönenberger
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Keywords:piperidino acetonitriles acetonitriles piperidino
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Item ID:18211
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