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Reactions of alpha -aminonitriles. VI. Reactions of aliphatic-substituted alpha -aminoacetonitriles with metallic sodium in toluene

Thies, Heinrich ; Schönenberger, Helmut ; Qasba, P. K.



Abstract

To 17.2 g. Na in 250 ml. PhMe 0.75 mole I in 250 ml. PhMe was added dropwise with slow shaking, and the mixt. shaken 4 hrs. at 120 Deg to give mixts. of II and III (R, R1, b.p. II, % yield II, b.p. III, and % yield III given): H, Me, b720 130-2 Deg, 43.3, b15 148 Deg, 21.8; H, Pr, b725 171-8 Deg, 42.1, b15 173-5 Deg, 21.2; Me, Me, b720 145-8 Deg, 51.9, b0.4 110-13 Deg, 7.8; Me, Et, b715 173-5 ...

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