Thies, H., Schönenberger, Helmut und Zeller, A. (1965) Reactions of Schiff bases. XI. Effect of heavy metal halides on the reaction between Grignard-type compounds and Schiff bases. Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft 298 (1), S. 26-33.
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Zusammenfassung
cf. CA 54, 18432c; 55, 18634c; 56, 363a. The reaction between benzylidenebutylamine (I) with the Grignard reagent iso-PrMgBr2 was used as model reaction to study the influence of heavy metal halides on products and yield. Without any metal halide addn., the reaction products were chiefly alpha -phenyl-alpha -butylamino-beta -methylpropane (II) and some benzylbutylamine (III) as a monomeric redn. ...
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| Dokumentenart: | Artikel | ||||
|---|---|---|---|---|---|
| Datum: | 1965 | ||||
| Zusätzliche Informationen (Öffentlich): | CAN 62:74285 39 Organometallic and Organometalloidal Compounds 4169-62-4; 6867-97-6 (Derived from data in the 7th Collective Formula Index (1962-1966); 7439-95-4 (Magnesium) (compds., alkyl halo, reaction with alkyl halides, catalysts and); 1137-52-6P (Benzylamine, N-butyl-alpha -isopropyl-); 2403-22-7P (Benzylamine, N-butyl-) Role: PREP (Preparation) (formation from N-benzylidenebutylamine and isopropylmagnesium halides); 1165-52-2P (Ethylenediamine, N,N'-dibutyl-1,2-diphenyl-, meso-) Role: PREP (Preparation) (formation in N-benzylidenebutylamine reaction with isopropylmagnesium halides); 109-73-9P (Butylamine) Role: PREP (Preparation) (formation of, in N-benzylidenebutylamine reaction with isopropylmagnesium halides); 7705-07-9 (Titanium chloride, TiCl3) (in N-benzylidenebutylamine reaction with isopropylmagnesium halides); 1077-18-5 (Butylamine, N-benzylidene-) (reaction with isopropylmagnesium halides in presence of transition metal halides); 920-39-8 (Magnesium, bromoisopropyl-); 1068-55-9 (Magnesium, chloroisopropyl-); 1068-56-0 (Magnesium, iodoisopropyl-) (reaction with N-benzylidenebutylamine in presence of transition metal halides); 7446-70-0 (Aluminum chloride); 7447-39-4 (Copper chloride, CuCl2); 7487-94-7 (Mercury chloride, HgCl2); 7646-79-9 (Cobalt chloride, CoCl2); 7646-85-7 (Zinc chloride); 7705-08-0 (Iron chloride, FeCl3); 7718-54-9 (Nickel chloride, NiCl2); 7718-98-1 (Vanadium chloride, VCl3); 7758-95-4 (Lead chloride, PbCl2); 7773-01-5 (Manganese chloride, MnCl2); 10025-73-7 (Chromium chloride, CrCl3); 10043-52-4 (Calcium chloride) (N-benzylidenebutylamine reaction with isopropylmagnesium halides in presence of) | ||||
| Institutionen: | Chemie und Pharmazie > Institut für Pharmazie > Entpflichtete oder im Ruhestand befindliche Professoren > Prof. Schönenberger | ||||
| Identifikationsnummer: |
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| Stichwörter / Keywords: | Schiff bases (Grignard reaction of, in presence of transition metal halides) Transition metal halides (Grignard reaction with Schiff bases in presence of) Grignard reaction (with Schiff bases in presence of transition metal halides) | ||||
| Dewey-Dezimal-Klassifikation: | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status: | Veröffentlicht | ||||
| Begutachtet: | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden: | Unbekannt / Keine Angabe | ||||
| Eingebracht am: | 18 Nov 2010 11:09 | ||||
| Zuletzt geändert: | 24 Mai 2018 12:20 | ||||
| Dokumenten-ID: | 18215 |
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