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Reactions of Schiff bases. XI. Effect of heavy metal halides on the reaction between Grignard-type compounds and Schiff bases

Thies, H. ; Schönenberger, Helmut ; Zeller, A.


cf. CA 54, 18432c; 55, 18634c; 56, 363a. The reaction between benzylidenebutylamine (I) with the Grignard reagent iso-PrMgBr2 was used as model reaction to study the influence of heavy metal halides on products and yield. Without any metal halide addn., the reaction products were chiefly alpha -phenyl-alpha -butylamino-beta -methylpropane (II) and some benzylbutylamine (III) as a monomeric redn. ...


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