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Triplet state relaxation processes of the OLED emitter Pt(4,6-dFppy)(acac)

Rausch, A. F. ; Thompson, M. E. ; Yersin, Hartmut


The emitting triplet state of Pt(4,6-dFppy)(acac) doped into n-octane is studied at cryogenic temperatures by site-selective high-resolution optical spectroscopy. The investigations reveal a very specific zero-field splitting (ZFS) pattern of the emitting T₁ state and the individual deactivation times of the substates to the singlet ground state S(0). Spin-lattice relaxation (SLR) processes ...


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