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Coordinative stabilization of a phosphido-phosphinidene ligand

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Scherer, Otto ; Winter, Rainer F. ; Wolmershäuser, Gotthelf
Date of publication of this fulltext: 15 Dec 2010 07:30


The phosphido-phosphinidene coordination mode Cof a P2 ligand has been realized in the trinuclear complex [(TaL)3(P4)(P2)]2(L = 1,3-But2C5H3); structural proof was obtained by X-ray structure determination of the [(TaL)3(P4{Fe(CO)4}MP2)] derivative 3.

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