Coordinative stabilization of a phosphido-phosphinidene ligand

URN to cite this document:: urn:nbn:de:bvb:355-epub-187622
DOI to cite this document:: 10.5283/epub.18762

Scherer, Otto ; Winter, Rainer F. ; Wolmershäuser, Gotthelf

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Date of publication of this fulltext: 15 Dec 2010 07:30

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Abstract

The phosphido-phosphinidene coordination mode Cof a P2 ligand has been realized in the trinuclear complex [(TaL)3(P4)(P2)]2(L = 1,3-But2C5H3); structural proof was obtained by X-ray structure determination of the [(TaL)3(P4{Fe(CO)4}MP2)] derivative 3.

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