Stepwise oxidation of three communicating metal centres: electrochemistry of trinuclear trindenyl complexes of manganese or rhodium

URN to cite this document:: urn:nbn:de:bvb:355-epub-187675
DOI to cite this document:: 10.5283/epub.18767

Winter, Rainer F. ; Pierce, David T. ; Geiger, William E. ; Lynch, Thomas J.

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Date of publication of this fulltext: 15 Dec 2010 07:24

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Abstract

Trinuclear manganese or rhodium complexes of the trindenyl (Td) ligand undergo three separate 1 e–-oxidation reactions, with an abnormally large separation in potentials between the second and third oxidations of [Td{Rh3(cod)3}].

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