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Polarized emission from Ba[Pt(CN)₄] 4H₂O single crystals under high pressure

Stock, M. ; Yersin, Hartmut


Abstract

The emission spectra of single crystal Ba[Pt(CN)₄]•4H₂O were measured from 0 to 23 kbar for the two electronic transitions which are polarized with E parallel c and E perpendicular C. They exhibit a red-shift of -280 cm⁻¹/kbar and -195 cm⁻¹/kbar, respectively. The red-shift is explained by a pressure induced reduction of the intermolecular separation R in the direction of the linear chain ...

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