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Phase transformation in Y₂[Pt(CN)₄]₃•2H₂O

Yersin, Hartmut ; Gliemann, G. ; Räde, H.


Abstract

Y₂[Pt(CN)₄]₃•2H₂O (YCP) crystallizes in a columnar structure type with a mean in-chain Pt-Pt distance of R = 3.18 Å. At T(c) = (218.5 ± 1) K YCP undergoes a first order phase transformation which is investigated spectroscopically (polarized emission) and thermodynamically (specific heat and differential thermal analysis). It is possible to record polarized emission spectra from the high ...

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