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Energy transfer from linear stacks of tetracyanoplatinates(II) to rare earth ions

Yersin, Hartmut


Abstract

M₂[Pt(CN)₄]₃•nH₂O compounds (with M³⁺ = Sm³⁺, Eu³⁺, Tb³⁺, ...) represents a new solid state class for investigations of nonradiative excitation energy transfer. The donors are linear stacks (columns) of square planar [Pt(CN)₄]²⁻ complexes and the acceptors are rare earth ions which are located between the stacks. Radiationless energy transfer and sharp line rare earth ion emission have been ...

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