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High pressure tuning of optical transitions in Mg[Pt(CN)₄]•7H₂O

Stock, M. and Yersin, Hartmut (1978) High pressure tuning of optical transitions in Mg[Pt(CN)₄]•7H₂O. Solid State Communications 27, pp. 1305-1308.

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Abstract

Mg[Pt(CN)₄]•7H₂O belongs to the class of tetracyanoplatinates(II) which crystallize in columnar structures. In different Mx[Pt(CN)₄]•yH₂O (MCP) single crystals the in-chain Pt—Pt-distance R varies between 3.67 Å (NaCP) and 3.15 Å (MgCP). Two optical transitions can be observed in polarized emission with the electric field vector E either parallel or perpendicular to the columnar (c)-axis. ...

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Item type:Article
Date:1978
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:19895
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