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High pressure tuning of optical transitions in Mg[Pt(CN)₄]•7H₂O

Stock, M. ; Yersin, Hartmut


Abstract

Mg[Pt(CN)₄]•7H₂O belongs to the class of tetracyanoplatinates(II) which crystallize in columnar structures. In different Mx[Pt(CN)₄]•yH₂O (MCP) single crystals the in-chain Pt—Pt-distance R varies between 3.67 Å (NaCP) and 3.15 Å (MgCP). Two optical transitions can be observed in polarized emission with the electric field vector E either parallel or perpendicular to the columnar (c)-axis. ...

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