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Transition energy tuning from 3.3 - 1.4 eV in the system Mx[Pt(CN)₄]•mH₂O

Yersin, Hartmut, Hidvegi, I., Gliemann, G. and Stock, M. (1979) Transition energy tuning from 3.3 - 1.4 eV in the system Mx[Pt(CN)₄]•mH₂O. Physical Review B (PRB) 19, pp. 177-180.

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The electronic transition energies of the Mx[Pt²⁺(CN)₄]•mH₂O compounds, crystallizing in columnar structures, depend strongly on the Pt-Pt distance R in the direction of the columns. R can be varied by substituting M and/or by application of high pressure. Using three different compounds {Na₂[Pt(CN)₄]•3H₂O, Ca[Pt(CN)₄]•5H₂O, Mg[Pt(CN)₄]•7H₂O} and applying hydrostatic pressures up to 38 kbar it is ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:19897
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