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Polarized and time-resolved spectroscopy of single-crystal Ba[Pt(CN)₄]•4H₂O, a pseudo-one-dimensional system

Gerhard, V. ; Pfab, W. ; Reisinger, J. ; Yersin, Hartmut


Polarized time-resolved emission spectra of highly anisotropic Ba[Pt(CN)₄]•4H₂O single crystal were measured at 295 K, 80 K and 1.7 K. Several localized and delocalized excited states with different time-behavior are observed. At high excitation intensities there are indications of a cooperative exciton effect.

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