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Franck-Condon analysis of transition-metal complexes

Yersin, Hartmut ; Otto, H. ; Zink, J. I. ; Gliemann, G.


The vibronic structure in the single crystal polarized luminescence spectra of K₂[Pt(CI₄], K₂[PtBr₄], and K₂[Co(CN)₆]•3H₂O is analyzed by Franck-Condon calculations. The various degrees of approximation in the Franck-Condon calculations are described. The differentes in the calculated vibronic intensities and in the calculated excited state distortions resulting from the approximations are ...


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