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Wilhelm, S. ; Wolfbeis, Otto S.

Opto-Chemical Micro-Capillary Clocks

Wilhelm, S. und Wolfbeis, Otto S. (2010) Opto-Chemical Micro-Capillary Clocks. Mikrochimica acta 171 (3-4), S. 211-216.

Veröffentlichungsdatum dieses Volltextes: 18 Mrz 2011 06:41
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.19954


Zusammenfassung

Opto-chemical capillary clocks are presented that are based on the measurement of a colored segment in a microchannel (a capillary). Color is created by a chromogenic chemistry involving the oxidation of a (virtually colorless) leuco-dye. Poly(ethylene glycol) (PEG) is used as a solvent, and indigo and thioindigo (in their reduced leuco forms) act as oxygen-sensitive dyes. The clock is started by ...

Opto-chemical capillary clocks are presented that are based on the measurement of a colored segment in a microchannel (a capillary). Color is created by a chromogenic chemistry involving the oxidation of a (virtually colorless) leuco-dye. Poly(ethylene glycol) (PEG) is used as a solvent, and indigo and thioindigo (in their reduced leuco forms) act as oxygen-sensitive dyes. The clock is started by removing one seal at the end of the capillary. A visible color change occurs as air diffuses into the microchannel due to an irreversible color reaction. The length of the colored segment is proportional to the time elapsed. PEGs of different average molar mass affect the diffusion rate of oxygen in the microchannel and thereby affect the rate of the migration of the color front. Both temperature and relative humidity exert a strong effect. Six types of such clocks are described that enable times to be determined in the range from 1 day to 6 months, possibly of even decades.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftMikrochimica acta
Verlag:SPRINGER WIEN
Ort der Veröffentlichung:WIEN
Band:171
Nummer des Zeitschriftenheftes oder des Kapitels:3-4
Seitenbereich:S. 211-216
Datum24 September 2010
InstitutionenChemie und Pharmazie > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Antje J. Bäumner, ehemals Prof. Wolfbeis)
Identifikationsnummer
WertTyp
10.1007/s00604-010-0456-4DOI
Stichwörter / KeywordsTIME-TEMPERATURE INTEGRATOR; POLYETHYLENE-GLYCOL; FRESHNESS; INDIGO; REDUCTION; PHOSPHATE; Optical timer; Chromogenic chemistry; Indigo; Oxygen; Clock; Poly(ethylene glycol)
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetUnbekannt / Keine Angabe
An der Universität Regensburg entstandenUnbekannt / Keine Angabe
Dokumenten-ID19954

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