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Opto-Chemical Micro-Capillary Clocks
Wilhelm, S. und Wolfbeis, Otto S.
(2010)
Opto-Chemical Micro-Capillary Clocks.
Mikrochimica acta 171 (3-4), S. 211-216.
Veröffentlichungsdatum dieses Volltextes: 18 Mrz 2011 06:41
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.19954
Zusammenfassung
Opto-chemical capillary clocks are presented that are based on the measurement of a colored segment in a microchannel (a capillary). Color is created by a chromogenic chemistry involving the oxidation of a (virtually colorless) leuco-dye. Poly(ethylene glycol) (PEG) is used as a solvent, and indigo and thioindigo (in their reduced leuco forms) act as oxygen-sensitive dyes. The clock is started by ...
Opto-chemical capillary clocks are presented that are based on the measurement of a colored segment in a microchannel (a capillary). Color is created by a chromogenic chemistry involving the oxidation of a (virtually colorless) leuco-dye. Poly(ethylene glycol) (PEG) is used as a solvent, and indigo and thioindigo (in their reduced leuco forms) act as oxygen-sensitive dyes. The clock is started by removing one seal at the end of the capillary. A visible color change occurs as air diffuses into the microchannel due to an irreversible color reaction. The length of the colored segment is proportional to the time elapsed. PEGs of different average molar mass affect the diffusion rate of oxygen in the microchannel and thereby affect the rate of the migration of the color front. Both temperature and relative humidity exert a strong effect. Six types of such clocks are described that enable times to be determined in the range from 1 day to 6 months, possibly of even decades.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Mikrochimica acta | ||||
| Verlag: | SPRINGER WIEN | ||||
|---|---|---|---|---|---|
| Ort der Veröffentlichung: | WIEN | ||||
| Band: | 171 | ||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 3-4 | ||||
| Seitenbereich: | S. 211-216 | ||||
| Datum | 24 September 2010 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Antje J. Bäumner, ehemals Prof. Wolfbeis) | ||||
| Identifikationsnummer |
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| Stichwörter / Keywords | TIME-TEMPERATURE INTEGRATOR; POLYETHYLENE-GLYCOL; FRESHNESS; INDIGO; REDUCTION; PHOSPHATE; Optical timer; Chromogenic chemistry; Indigo; Oxygen; Clock; Poly(ethylene glycol) | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Unbekannt / Keine Angabe | ||||
| An der Universität Regensburg entstanden | Unbekannt / Keine Angabe | ||||
| Dokumenten-ID | 19954 |
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