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Tetraamminelithium triamminelithium trisulfide, [Li(NH₃)₄][Li(NH₃)₃S₃]
Guentner, Christian und Korber, Nikolaus (2012) Tetraamminelithium triamminelithium trisulfide, [Li(NH₃)₄][Li(NH₃)₃S₃]. Acta Crystallographica Section E 68, i84-i85.Veröffentlichungsdatum dieses Volltextes: 30 Jan 2013 12:33
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Zusammenfassung (Deutsch)
The title compound, [Li(NH3)4]+[Li(NH3)3S3]-, an ammoniate of the previously unknown lithium trisulfide, was obtained from the reaction of lithium and sulfur in liquid ammonia. The asymmetric unit consists of two crystallographically independent formula units. The [Li(NH3)4]+ cations are close to regular LiN4 tetrahedra. The anions contain LiSN3 tetrahedra; the S-S-S bond angles are 110.43 (5) ...
The title compound, [Li(NH3)4]+[Li(NH3)3S3]-, an ammoniate of the previously unknown lithium trisulfide, was obtained from the reaction of lithium and sulfur in liquid ammonia. The asymmetric unit consists of two crystallographically independent formula units. The [Li(NH3)4]+ cations are close to regular LiN4 tetrahedra. The anions contain LiSN3 tetrahedra; the S-S-S bond angles are 110.43 (5) and 109.53 (5)°. In the crystal, the components are linked by multiple N-H...S hydrogen bonds. A weak N-H...N hydrogen bond is also present.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Acta Crystallographica Section E | ||||
| Verlag: | International Union of Crystallography | ||||
|---|---|---|---|---|---|
| Band: | 68 | ||||
| Seitenbereich: | i84-i85 | ||||
| Datum | November 2012 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber | ||||
| Identifikationsnummer |
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| Dewey-Dezimal-Klassifikation | ?? BX ?? ?? GR ?? ?? PN2000 ?? ?? QR ?? 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Ja | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-200128 | ||||
| Dokumenten-ID | 20012 |
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