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Tetraamminelithium triamminelithium trisulfide, [Li(NH₃)₄][Li(NH₃)₃S₃]

URN to cite this document:
Guentner, Christian ; Korber, Nikolaus
License: Creative Commons: Attribution 3.0
PDF - Published Version
Date of publication of this fulltext: 30 Jan 2013 12:33

Abstract (German)

The title compound, [Li(NH3)4]+[Li(NH3)3S3]-, an ammoniate of the previously unknown lithium trisulfide, was obtained from the reaction of lithium and sulfur in liquid ammonia. The asymmetric unit consists of two crystallographically independent formula units. The [Li(NH3)4]+ cations are close to regular LiN4 tetrahedra. The anions contain LiSN3 tetrahedra; the S-S-S bond angles are 110.43 (5) ...


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