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Time-resolved spectroscopy and energy transfer from linear [Pt(CN)₄]²⁻ chains to rare-earth cations in Ln₂[Pt(CN)₄]₃•nH₂O single crystals

v. Ammon, W. ; Yersin, Hartmut ; Gliemann, G.


Abstract

Nonradiative energy transfer from linear stacks of [Pt(CN)₄]²⁻ complexes to rare-earth cations in Ln₂[Pt(CN)₄]₃•nH₂O single crystals was investigated by time-resolved emission spectroscopy. The transfer rates were found to vary in the range (10⁸ - 10⁹) s⁻¹.


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