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Spectroscopic behavior of quasi-one-dimensional linear chains in Mg[Pt(CN)₄]•7H₂O single crystals

Yersin, Hartmut and Gliemann, G. (1975) Spectroscopic behavior of quasi-one-dimensional linear chains in Mg[Pt(CN)₄]•7H₂O single crystals. Z. Naturforsch. B 30 b, pp. 183-190.

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Abstract

In the direction of the crystallographic c-axis Mg[Pt(CN)₄]•7H₂O has a relatively low Pt-Pt-distance (3.15 Å at 300 K). Thus the optical behavior shows inter-molecular interactions. Single crystal polarized emission and absorption spectra were measured between 300 K and 5 K. In this temperature range the emission peaks shift to the red by about 1100 cm⁻¹. This is attributed to a decrease in ...

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Item type:Article
Date:1975
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:20104
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