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Spectroscopic behavior of quasi-one-dimensional linear chains in Mg[Pt(CN)₄]•7H₂O single crystals

Yersin, Hartmut ; Gliemann, G.


In the direction of the crystallographic c-axis Mg[Pt(CN)₄]•7H₂O has a relatively low Pt-Pt-distance (3.15 Å at 300 K). Thus the optical behavior shows inter-molecular interactions. Single crystal polarized emission and absorption spectra were measured between 300 K and 5 K. In this temperature range the emission peaks shift to the red by about 1100 cm⁻¹. This is attributed to a decrease in ...


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