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Crystal structure of Cs₂[Pt(CN)₄]•H₂O

Otto, H. H. ; Schulz, H. ; Thiemann, K. H. ; Yersin, Hartmut ; Gliemann, G.


Abstract

The crystal structure of Cs₂[Pt(CN)₄]•H₂O has been determined from X-ray diffraction data and refined to a conventional R value of 0.068 from 2210 reflections. The compound is hexagonal, a = 9.687(2) and c = 19.336(6) Å, space group C²₆-P6₁, Z = 6. The given atomic coordinates represent the absolut configuration. The nearly square planar [Pt(CN)₄]²⁻ groups from a helix with respect to the c axis. ...

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