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Emission of properties of Ir(ppy)₃ and Ir(ppy)₂(CO)(Cl). Compounds with different transition types

Finkenzeller, Walter J. ; Stoessel, P. ; Kulikova, M. V. ; Yersin, Hartmut


Emission properties of Ir(ppy)₃ and of Ir(ppy)₂(CO)(Cl) (ppy⁻ = 2-phenylpyridinate) are investigated between 1.2 K and 300 K. Distinct differences are found for the emission spectra, decay behavior, and relaxation dynamics. For both compounds, the emission spectra are broad or only moderately resolved, nevertheless, from time-resolved investigations individual properties of the triplet substates ...


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