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Identification of roxarsone metabolites produced in the system: soil – chlorinated water – light by using HPLC-ICP-MS/ESI-MS, HPLC-ESI-MS/MS and high resolution mass spectrometry (ESI-TOF-MS)

URN to cite this document:
urn:nbn:de:bvb:355-epub-205648
Arroyo-Abad, U. ; Mattusch, J. ; Möder, M. ; Elizalde-Gonzàlez, M.P. ; Wennrich, R. ; Matysik, Frank-Michael
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Date of publication of this fulltext: 18 Apr 2011 12:35


Abstract

Roxarsone (4-hydroxy-3-nitrophenylarsonic acid) in contact with soil of volcanic origin and chlorine containing water generated a set of organoarsenicals. The transformation products were identified with element-specific (ICP-MS) as well as molecular-specific (ESI-MS) detection after their HPLC separation. The identification of the main transformation products by means of ESI-MS, ESI-MS/MS and ...

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