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Comparison of detection performance of UV and electrochemical detection in nonaqueous capillary electrophoresis for a range of different capillary inner diameters

Blasco, S. ; Kortz, L. ; Matysik, Frank-Michael


A systematic comparison of UV and electrochemical detection (ED) in conjunction with NACE has been performed for capillaries with different ids ranging from 75 down to 2 μm. Ferrocene, (ferrocenylmethyl)trimethylammonium acetate, atropine and scopolamine served as model analytes. All studies were done using an ACN-based nonaqueous electrophoresis buffer. For the comparison of detection ...


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