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Energy transfer-based lifetime sensing of chloride using a luminescent transition metal complex

Huber, Christian ; Werner, Tobias ; Krause, Christian ; Klimant, Ingo ; Wolfbeis, Otto S.
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Date of publication of this fulltext: 06 Jun 2011 13:43


Abstract

A bulk membrane responsive to chloride has been developed containing a luminescent ruthenium complex placed in close proximity to the pH-sensitive absorber bromothymol blue (BTB), both contained in a plasticized poly(vinyl chloride) (PVC) membrane along with an anion-selective carrier. The response is based on the co-extraction of chloride along with protons from the aqueous sample into the PVC ...

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