Energy transfer-based lifetime sensing of chloride using a luminescent transition metal complex

DOI to cite this document:: 10.5283/epub.21008

Huber, Christian ; Werner, Tobias ; Krause, Christian ; Klimant, Ingo ; Wolfbeis, Otto S.

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Date of publication of this fulltext: 06 Jun 2011 13:43

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Item type:	Article
Journal or Publication Title:	Analytica Chimica Acta
Publisher:	Elsevier
Volume:	364
Page Range:	pp. 143-151
Date:	1998
Institutions:	Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Antje J. Bäumner, formerly Prof. Wolfbeis)
Keywords:	Energy transfer; Decay time; Chloride sensor
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Unknown
Created at the University of Regensburg:	Unknown
Item ID:	21008

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Abstract

A bulk membrane responsive to chloride has been developed containing a luminescent ruthenium complex placed in close proximity to the pH-sensitive absorber bromothymol blue (BTB), both contained in a plasticized poly(vinyl chloride) (PVC) membrane along with an anion-selective carrier. The response is based on the co-extraction of chloride along with protons from the aqueous sample into the PVC ...

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