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Glycosylation of Cardenolide Aglycones in the Leaves of Nerium oleander L.

Paper, D. ; Franz, Gerhard



Abstract

Application of [14C]-progesterone to the leaves of Nerium oleander L. (Apocynaceae) resulted in the formation of [14C]-digitoxigenin and [14C]-oleandrigenin glycosides; the labelled aglycones were obtained after hydrolysis from the cardenolide extract. Both radioactive cardenolide aglycones were further transformed by the leaves of Nerium oleander L. to the corresponding 3-O-β-glucosides ...

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