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Conductance of electrolytes in 1-propanol solutions from −40 to 25°C
Barthel, Josef, Wachter, R., Schmeer, Georg und Hilbinger, H. (1986) Conductance of electrolytes in 1-propanol solutions from −40 to 25°C. Journal of Solution Chemistry 15 (7), S. 531-550.Veröffentlichungsdatum dieses Volltextes: 14 Dez 2011 08:31
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.22949
Zusammenfassung
Conductance data for solutions of LiCl, NaBr, NaI, KI, KSCN, RbI, Et4NI, Pr4NI, Bu4NI, Bu4NClO4, n-Am4NI, i-Am4NI, n-Hept4NI, Me2Bu2NI, MeBu3NI, EtBu3NI, i-Am3BuNI, and i-Am3BuNBPh4 in 1-propanol at –40, –30, –20, –10, 0, 10, and 25°C are communicated and discussed. Evaluation of the data is performed on the basis of a conductance equation that includes a term in c3/2. Single ion conductances at ...
Conductance data for solutions of LiCl, NaBr, NaI, KI, KSCN, RbI, Et4NI, Pr4NI, Bu4NI, Bu4NClO4, n-Am4NI, i-Am4NI, n-Hept4NI, Me2Bu2NI, MeBu3NI, EtBu3NI, i-Am3BuNI, and i-Am3BuNBPh4 in 1-propanol at –40, –30, –20, –10, 0, 10, and 25°C are communicated and discussed. Evaluation of the data is performed on the basis of a conductance equation that includes a term in c3/2. Single ion conductances at 25 and 10°C are determined with the help of transference numbers t o + (KSCN/PrOH); the data are compared to data estimated by other methods. Ion-pair association constants and their temperature dependence are discussed in terms of contact and solvent separated ion pairs, and the role of non-coulombic forces is shown with the help of an appropriate splitting of the Gibbs energy of ion-pair formation.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Journal of Solution Chemistry | ||||
| Verlag: | Plenum; Kluwer; Springer | ||||
|---|---|---|---|---|---|
| Band: | 15 | ||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 7 | ||||
| Seitenbereich: | S. 531-550 | ||||
| Datum | 1986 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Entpflichtete oder im Ruhestand befindliche Professoren > Prof. Dr. Georg Schmeer | ||||
| Identifikationsnummer |
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| Stichwörter / Keywords | Electrolyte conductance - single ion conductance - ion-pair formation - non-coulombic interactions - 1-propanol solutions - alkali metal salts - tetraalkylammonium salts | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Unbekannt / Keine Angabe | ||||
| An der Universität Regensburg entstanden | Unbekannt / Keine Angabe | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-229491 | ||||
| Dokumenten-ID | 22949 |
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