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The Temperature Dependence of the Properties of Electrolyte Solutions. III. Conductance of Various Salts at High Concentrations in Propylene Carbonate at Temperatures from − 45°C to + 25°C

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Barthel, Josef ; Gores, H.-J. ; Schmeer, Georg
Date of publication of this fulltext: 14 Dec 2011 08:22


Specific conductances of Et4NPF6, Pr4NPF6, Bu4NPF6, LiPF6, KPF6, LiClO4, and KSCN in propylene carbonate were studied at high concentrations in the temperature range from +25°C to -45°C. Data are fitted by a least-squares method to a four-parametric empirical equation, yielding the maximum specific conductance κmax and the corresponding concentration μ. Within the frame-work of a hydro-dynamic ...


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