Absorption and emission spectra of a single-crystal (maleonitriledithiolato)palladate(II) complex

URN to cite this document:: urn:nbn:de:bvb:355-epub-230049
DOI to cite this document:: 10.5283/epub.23004

Güntner, W. ; Gliemann, G. ; Kunkely, Horst ; Reber, C. ; Zink, J. I.

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Date of publication of this fulltext: 21 Dec 2011 06:44

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Abstract

The polarized optical absorption and emission of single crystals of [(C2H5)4N]2[Pd(mnt)2] (mnt = [S2C2(CN)2]2-) at temperatures 3 K less-than-or-equal-to T less-than-or-equal-to 295 K are reported. The lowest excited states are due to 1,3B3g and 1,3B2u terms with metal-to-ligand charge-transfer and ligand-centered character, respectively. Vibronic structure is observed on the lowest energy ...