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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-230118
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.23011
Alternative Links zum Volltext:DOI
Zusammenfassung
Photolysis of methylcobalamin (Co(III)corrin(CH3)L + H2O + O2 �> Co(III)(H2O)L + H2CO + OH-) shows a pronounced wave-length dependence. It is suggested that the reactive excited state is of the ligand-to-ligand charge transfer (LLCT) type and involves the promotion of an electron from the Co-C sigma-bond to a pi*(corrin) orbital. This LLCT transition mixes with the pipi*(corrin) transitions. ...
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