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Von Cp+2Nb(η2-S2)H zu CP+3Nb3S12: Reaktivitätsstudien an Niobocensulfiden ( = FROM CP+2NB(ETA-2-S2)H TO CP+3NB3S12 - REACTIVITY STUDIES ON NIOBOCENE SULFIDES)

Brunner, H., Gehart, G., Meier, W., Wachter, Joachim and Nuber, B. (1993) Von Cp+2Nb(η2-S2)H zu CP+3Nb3S12: Reaktivitätsstudien an Niobocensulfiden ( = FROM CP+2NB(ETA-2-S2)H TO CP+3NB3S12 - REACTIVITY STUDIES ON NIOBOCENE SULFIDES). Journal of Organometallic Chemistry 454 (1-2), pp. 117-122.

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Abstract

The reaction of Cp+2bBH4 with sulfur gives two isomers of composition Cp+2NbS2H (3, 4) and Cp+2NbS3H (5). The structures of 3-5 have been investigated by IR and H-1 NMR spectroscopic means. X-Ray diffraction analyses have been performed on 3 and 4. These investigations demonstrate that 3 and 4 are niobocene derivatives, in which either a eta2-S-2(2)--ligand and a hydride (3) or a S2- and a SH- ...

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Item type:Article
Date:1993
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1016/0022-328X(93)83232-KDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:23034
Owner only: item control page

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