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Reactivity studies on tantalocene(sulfido)hydride Cp′2Ta(S)H (Cp′= ButC5H4): cycloaddition on and protonation of the Ta=S ligand

URN to cite this document:
urn:nbn:de:bvb:355-epub-230359
Brunner, H. ; Kubicki, Marek M. ; Leblanc, J. C. ; Moise, C. ; Volpato, F. ; Wachter, Joachim
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Date of publication of this fulltext: 04 Jan 2012 08:43


Abstract

Reactions of the tantalocene(sulfido)hydride Cp'2Ta(=S)H with PhNCS and HCl exhibit a surprisingly low metal-hydride reactivity; the Ta=S bond being involved either in a [2 + 2] cycloaddition or a protonation.


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