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Reactivity studies on tantalocene(sulfido)hydride Cp′2Ta(S)H (Cp′= ButC5H4): cycloaddition on and protonation of the Ta=S ligand

Brunner, H., Kubicki, Marek M., Leblanc, J. C., Moise, C., Volpato, F. and Wachter, Joachim (1993) Reactivity studies on tantalocene(sulfido)hydride Cp′2Ta(S)H (Cp′= ButC5H4): cycloaddition on and protonation of the Ta=S ligand. Journal of the Chemical Society, Chemical Communications (10), pp. 851-852.

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Abstract

Reactions of the tantalocene(sulfido)hydride Cp'2Ta(=S)H with PhNCS and HCl exhibit a surprisingly low metal-hydride reactivity; the Ta=S bond being involved either in a [2 + 2] cycloaddition or a protonation.


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Item type:Article
Date:1993
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1039/c39930000851DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:23035
Owner only: item control page

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