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Reactivity studies on tantalocene(sulfido)hydride Cp′2Ta(S)H (Cp′= ButC5H4): cycloaddition on and protonation of the Ta=S ligand
Brunner, H., Kubicki, Marek M., Leblanc, J. C., Moise, C., Volpato, F. and Wachter, Joachim (1993) Reactivity studies on tantalocene(sulfido)hydride Cp′2Ta(S)H (Cp′= ButC5H4): cycloaddition on and protonation of the Ta=S ligand. Journal of the Chemical Society, Chemical Communications (10), pp. 851-852.Date of publication of this fulltext: 04 Jan 2012 08:43
Article
DOI to cite this document: 10.5283/epub.23035
Abstract
Reactions of the tantalocene(sulfido)hydride Cp'2Ta(=S)H with PhNCS and HCl exhibit a surprisingly low metal-hydride reactivity; the Ta=S bond being involved either in a [2 + 2] cycloaddition or a protonation.
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| Item type | Article | ||||
| Journal or Publication Title | Journal of the Chemical Society, Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry (RSC) | ||||
|---|---|---|---|---|---|
| Number of Issue or Book Chapter: | 10 | ||||
| Page Range: | pp. 851-852 | ||||
| Date | 1993 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Unknown | ||||
| Created at the University of Regensburg | Unknown | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-230359 | ||||
| Item ID | 23035 |
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