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Neue Aspekte in der Chemie von Übergangsmetallpolysulfidkomplexen: Synthese und Kristallstrukturen von Cp′3Nb3S12 und Cp′3Nb3S10O (Cp′ = t-BuC5H4)
Brunner, Henri, Meier, W., Wachter, Joachim, Nuber, Bernd and Ziegler, M. L. (1990) Neue Aspekte in der Chemie von Übergangsmetallpolysulfidkomplexen: Synthese und Kristallstrukturen von Cp′3Nb3S12 und Cp′3Nb3S10O (Cp′ = t-BuC5H4). Journal of Organometallic Chemistry 381 (1), C7-C12.Date of publication of this fulltext: 09 Jan 2012 12:45
Article
DOI to cite this document: 10.5283/epub.23052
Abstract
Thermolysis of a mixture of Cp′4Nb2Sn (Cp′ = t-BuC5H4; n = 8, 9) results in the formation of the new niobium polysulfide complexes: Cp′3Nb3S12 (2), Cp′3Nb3S10O (3), Cp′3Nb3S10O (4) and Cp′4Nb4S13 (5). The structures of 2 and 3 have been established by X-ray diffraction studies. The complexes are characterized by an unusual variety of different sulfur ligands (up to five in 2), which is responsible for the absence of any metal-metal interaction.
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| Item type | Article | ||||
| Journal or Publication Title | Journal of Organometallic Chemistry | ||||
| Publisher: | Elsevier | ||||
|---|---|---|---|---|---|
| Volume: | 381 | ||||
| Number of Issue or Book Chapter: | 1 | ||||
| Page Range: | C7-C12 | ||||
| Date | 1990 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Unknown | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-230521 | ||||
| Item ID | 23052 |
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