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Improvement of (bipy)Pt(XR)₂ (X = O; S) type photosensitiezers by covalent dye attachment

Pevny, F., Zabel, Manfred, Winter, Rainer F., Rausch, A. F., Yersin, Hartmut, Tuczek, F. and Zalis, S. (2011) Improvement of (bipy)Pt(XR)₂ (X = O; S) type photosensitiezers by covalent dye attachment. Chemical Communications (47), pp. 6302-6304.

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Abstract

Irradiation into the dye-based absorption band of complexes
(tBu₂bipy)Pt(SR)₂ and (tBu₂bipy)Pt(OR)₂ where R denotes a
coumarine-based thiolate and alkoxolate substituent populates
the same excited triplet state as is obtained by excitation into the
much weaker (RX)₂Pt-tBu₂bipy (X = O, S) charge-transfer band.
This paves the way toward more efficient photosensitizers.


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Item type:Article
Date:2011
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1039/c0cc04443aDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:23519
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