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Tris[(1,4,7,10,13,16-hexa-oxacyclo-octa-deca-ne)rubidium] heptaantimonide-ammonia (1/4)

URN to cite this document:
urn:nbn:de:bvb:355-epub-237263
Mutzbauer, Fabian ; Korber, Nikolaus
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Date of publication of this fulltext: 11 Apr 2012 09:04


Abstract

The crystal structure of the title compound, [Rb(C12H24O6)]3[Sb7]·4NH3, fills the gap between the already known Zintl anion ammoniates {[Cs(18-crown-6)]3Sb7}2·9NH3 [Wiesler (2007). Dissertation, Universität Regensburg, Germany] and [K(18-crown-6)]3Sb7·4NH3 [Hanauer (2007). Dissertation, Universität Regensburg, Germany]. As in the two known compounds, the antimony cage anion in this crystal ...

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