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Vapor pressure measurements on nonaqueous electrolyte solutions. Part 6. Some remarks on integral equations

Barthel, Josef ; Kunz, Werner



Abstract

Various combinations of the hypernetted chain (HNC) equation with the mean spherical approxn. (MSA) and the Percus-Yevick (PY) equation are compared both for a well-known aq. 2-2 electrolyte model soln. and for real acetonitrile solns. Belloni's self-consistency test shows that classical HNC calcns. yield the best compressibility data for the two systems despite an apparently unrealistic g++ ...

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