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NMR relaxation study of tetrapentylammonium ions in acetonitrile solutions

Lang, Elmar ; Bradl, S. ; Kunz, Werner ; Turq, P.


NMR measurements of the spin-lattice relaxation rates of the 1H, 13C, and 14N nuclei and spin-echo self-diffusion coeffs. are reported for tetrapentylammonium bromide in acetonitrile solns. over a wide range of temps. and concns. The results are discussed in terms of overall and segmental motions of the aliph. chains of the org. ions. Order parameters characterizing the geometrical constraints ...


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